Toxophile is a rarely used word that means a lover of archery, bowmanship or a person skilled in the use of the bow and arrow. There are a few other words that you can use instead of toxophile that convey a similar meaning. These synonyms include archer, bowman, markswoman, marksman, and sagittarian. All of these words refer to someone who enjoys and is skilled in the use of the bow and arrow. If you are writing about a person who loves archery or is an expert in the sport, you can use any of these words to refer to them and convey the desired meaning.