The phrase "face to" has several synonymous expressions in the English language. Some of the most commonly used synonyms include "confronting," "directly opposite," "head-on," "vis-à-vis," "facing off," and "in front of." Each of these expressions carries a slightly different connotation and is used in various contexts. For example, "vis-à-vis" is often used to describe a meeting or conversation between two people, while "facing off" is more commonly used in competitive scenarios, such as a boxing match or sporting event. Regardless of the context, using different synonyms for "face to" can add variety and nuance to your language.